Vertical Alignment of Liquid Crystals Over a Functionalized Flexible Substrate

Substrate-induced bulk alignment of liquid crystals.

Dopant-Enhanced Vertical Alignment of Negative Liquid Crystals

A simple method for achieving high-contrast vertical alignment of high birefringence (Dn 0.28) negative dielectric anisotropic liquid crystal mixture using buffed polyimide substrates is demonstrated. By doping a positive, or non-polar dielectric anisotropic compound or mixture to the laterally difluorinated tolane liquid crystal host, an excellent vertical alignment was obtained. This alignmen...

Alignment of liquid crystals on a photosensitive substrate studied by surface optical second-harmonic generation

The adsorption kinetics and orientational ordering of 4(')-n-octyl-4-cyanobiphenyl (8CB) liquid crystal films evaporated onto photosensitive poly(vinyl-cinnamate) (PVCN) substrates were investigated by surface optical second-harmonic generation. The adsorption rate of the first monolayer decreases with increasing degree of photochemical modification of the polymer. The in-plane orientational an...

Photo-Induced Vertical Alignment of Liquid Crystals via In Situ Polymerization Initiated by Polyimide Containing Benzophenone

Vertical alignment of liquid crystal (LC) was achieved in an easy and effective way: in situ photopolymerization of dodecyl acrylate (DA) monomers initiated by polyimide based on 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 3,3′-dimethyl-4,4′-diaminodiphenyl methane (BTDA-DMMDA PI). The alignment behavior and alignment stabilities were characterized by a polarizing optical microscope (...

Self-alignment of liquid crystals in three-dimensional photonic crystals.

We report on the observation of self-alignment of nematic liquid crystals into colloidal photonic crystals, over distances much larger than the typical size of the voids between the spheres. We observe that the infiltrated structure possesses a unique optical axis that is determined by an intrinsic structural anisotropy of photonic crystal opals. We develop a simple model to describe this self-...